ࡱ>  Root EntryRoot Entry~@"FileHeader?DocInfo(HwpSummaryInformation.   !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~BodyText 8~0~PrvImage "PrvTextDocOptions ޢ~ޢ~Scripts ޢ~~JScriptVersion F DefaultJScriptC_LinkDocG  !"#$%&')*+,-./0123456789:;<=>@ABDEHIJKLMNOQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~8] <\><Metal-Ligand Cooperation Occurring at a Low-valent 1st-row Transition Metal Center > <\Դ><Transition metal adduct formations with small molecules such as N2, H2, CO and CO2 are drawing much attention due to their importance in developing synthetic catalysts for various industrial processes. In our laboratory, two methodologies are employed. Firstly, a bioorganometallic approach is utilized for CO2 conversion. The chemistry is inspired by an efficient enzymatic CO2 catalysis occurring at the active site of the carbon monoxide dehydrogenase (CODH). One of the main challenges in transition metal-based CO2 catalysis is to accomplish the high selectivity in producing a desired product. This may rely on the interaction of CO2 with a metal center. Since the binding and reactivity toward CO2 is controlled in part by the geometry of a L3Ni scaffold, we have explored the chemistry of low-valent nickel supported by PEP pincer systems (E = N, Si or P), in which a pseudo-tetrahedral or square planar geo>PNG  IHDRRsRGBgAMA a pHYsodIDATx^읍uUzRMI1ym0-%ǛG!BY ԄB!ljB!B65!B!B! @M!Bx&B!d2?ҞK<@v2 ?Tky˿!p+|r};@N%{~@qĊ~_ //r9JM78Z.= >~-@ᡇ @}֫}oʂd۵z%=k:D?]mwZÌ͞K-C32\GZӁ(w$F!ni ח $^h́_|ͻC~QcͷW@A呥1p;y?µ2er]6><{{.5~k s_٫Ƈµ&eɈb>u= MrÒO_Zg=GbǽY}o5:./5[z ؛4^xȼp&yK@ً(_g顸~i-rf=/c P %$/sz`x|=P}c;8!Xl <ۮ/!sۏ$so/< ER|/^&ok'ljׄs wX'(ok sUKr~N+Hrzdz}\jppC݂t_Mpsï_/Ou~(͸Zw>Ix_y9)׺}9$CaAk>V0WIro^Ρ5kv :{ddRjcCQĢ>ڣ~Ӳ4ۓkɸ<㢏/_|KQ&s%5[/Ttyxޗẜy\ڗ[}׽= Zimko:z0uҪY2\XzsEPv:P_8syƼ>!u9ߏ:.xÏ}CȾ sm=~=ƉA:C@M!sjRec uD@ fzx恚Bwŭ};k l/įC:\G@}6;M3텵'|H/>[KrY'=LQekWMe.1 ,rfAO\P?:s9^L+ WV#[(r8B*YC+5X(_n9$7ŷá;8kr8ahӁ6Ώ3wuҹhP |9soσB3Wj"QAKzrк;5ä[sN;=*2fc@-]=8.,`[SKuhN[ wlkd9| !y9JM78JWNdwVc4ԚP :)=oӇ 1ןs~b9?~ӌd5qQ| !<p&kZx.88CYrX6sO1' /;_r-yOf2Xz= re>Fsߏ6y=K.y웻2ۍl<_B!2\GC69m]~KoD&?!?p9\M~}qYjWwrk'8|=Q}OgzQ}CҲ#[6 ildzų{h.m󰾂 V+ F mQ"}(yvy=\jGjB/Dr#ʓf9Uz#rWշWF^ɓDm=c̖&V?G>J%`eJ/T"kcÕnq|26%+_ ʓھm~BQW9+QDT)G >Mh#ķ'xOX[FTǓmS\9,w"OעןDpchQW[ĦVEr+OF[{sX*Gz%aH[ʕ1ޓG}dC'TP6eo!1Q޾2Tn)}+W1-U?#5ȱJM78Vh>u^S"9if9UBQW9+Q~Z-_ۯ ,&/UUBfX_Py#CG%W~5ȱJM78TK6$ h Uoe]HYYvV!zEz%y:Q`mVV2 hz%t^u'ۜ菲c_@N[ qW"-zYYC}F2ў*•nqBUnqBUnqBUnqd6Ӎ㍕bx^6+{];[׶Zw+5XhRr?sʨ[۰숧ұհ}$CZ\Ͻʰ쁱ڰ쁱=ҫ>~?6$אܖފ*Ȏ-նh /!cDZ#YLl,K1{_515p&kY-Ŧ A˧ Ύikq\e[[/<[0m-{ <. ^lD/y-\GVH*1WٚKy+:[*~":mkq(k#xQ_d)D}-h] *rd㭡+TY[cx1Bg?+DvF•nqD6^NjdڕH_ccsx:$cOL m +WМ,Vg}/ؾCţmO,΋_({5x6 ="}džx6Otry=\3jyF1ސaݣz!9qXyJ78mc*>aݣzɨ;:mm˃:{:ڬ -_!>E1t^m> ֮x괏>N@o Z=P%Bڱ/]VV"(h*up&kY-Yg2+rǼm[&s+5Xj)zmHv ]K:FؤDpc$rtԶpc#ؼ` 6t[CO$zG]am\:F4Vf{wOp&kZZ;k[Ds:\/ʟX-zy9\#ǎh]oK~wOp&kZzFgp9XO鑯5gν7W}NWj"Ѫ%m߳Y:)v+6x#O6#:&D6ԫ H:%!*{=[<6DHo=]/sY[z}O>ʂ ,Ƴi3Z~?B6U:AekS6l'nqjBmhzb*`\oh^IY5~B%.z7+GD9|M>d <^^D*6+"{5E9e>BlL% Wj"Ѫe0lZVג{Xm=DsJ{6[Q_X'}Ta["ڔ,dzKbO7˕[ȶr ?ٛ[hDv~;.lLkS^|g} U֧-d_R5V-3;*k">,γUYΞ\% NfTR7Њ7M6z/d6A^N!Qo}zK+5Xh2-zU׊zia6Eڔ,nPbP U`(g/YRB˿B%([vbWcUiwr|-QX#aK,Dpc#شYІmڕH#D2cTɊ+>]ľ$ҷ8يg%ԲQձϼڬ:Y6٨島D:ԫʊճҲ=p&ҬIxϿՏ%ӿg߱x"qZʼܿ5Ԥ̹ʿ鰨UK$R5֒R5֒R5V-nb=尿ƨ7Ϛ]*[!=b",:gBO[Y@걯ETJM78>Po}ZrF[ [sDV/ڭ[re1"Gr(ڒWhW9=ꬬݰ$#ծ4>:$ҩVnJ巺0'w=ճ9Ϗ6'ݳ􈕅ʳձՅZR59<5[?^/%JM78X!}ur-ROw\^6'+5X`- !+5X㘥yz-oGx5xVmy5~f>+5X㘥皱#±ǚVΰ찿<6ռ[ԵDpclF^j}snﴦG^WTnSז6Vx:ebl>* bl̖yqNl-H:PV]^<'JdC^Jf8ۣLVb}QtWZzktzJM78ZZʽz!뫌AǖP,gKrFmϋbJ"@(/K]c}*DYޭ1B+'^rDWUb""b*}7& *G =p&kY-_Sӷ8]ǒٶ*^L3i[^ Q>V\́x1QNV%yVT⳼[cE~xV)rW,Tb"6% U%+5Xjim*G1\Q_^|(|^LsB33]%g/'qm\e /&ʹ&euʙO(>˻5׊,3SX|<! 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